PCRT.I.G.02

PCRT.I.G

02 (N,p,S)-Koordinatensystem

$d Q_{N}$	$=$	$d Q_{p, N} + d Q_{S, N}$	$d Q_{N} (p, S), d Q_{p, N} (S), d Q_{S, N} (p)$
$d Q_{p, N}$	$=$	$d H_{p, N}$	$d H_{p, N} (S)$
$d Q_{S, N}$	$=$	$0$
$d W_{N}$	$=$	$d W_{p, N} + d W_{S, N}$	$d W_{N} (p, S), d W_{p, N} (S), d W_{S, N} (p)$
$d W_{p, N}$	$=$	$d U_{p, N} - d H_{p, N}$	$d U_{p, N} (S)$
$d W_{S, N}$	$=$	$d U_{S, N}$	$d U_{S, N} (p)$
$d U_{N}$	$=$	$d U_{p, N} + d U_{S, N}$	$d U_{N} (p, S)$
$H$	$=$	$+ \frac{5}{2} n R T_{0} {(\frac{p}{p_{0}})}^{2 / 5} \exp (\frac{2}{5} \frac{S - S_{0}}{n R})$	$H (N, p, S)$
$U$	$=$	$+ \frac{3}{2} n R T_{0} {(\frac{p}{p_{0}})}^{2 / 5} \exp (\frac{2}{5} \frac{S - S_{0}}{n R})$	$U (N, p, S)$
$Q_{p 1, N} (S_{2}, S_{1})$	$=$	$+ \frac{5}{2} n R T_{0} {(\frac{p_{1}}{p_{0}})}^{2 / 5} [\exp (\frac{2}{5} \frac{S_{2}}{n R}) - \exp (\frac{2}{5} \frac{S_{1}}{n R})]$	$(p, S : p_{1} S_{1} \to p_{1} S_{2}), d N = 0$
$W_{p 1, N} (S_{2}, S_{1})$	$=$	$- n R T_{0} {(\frac{p_{1}}{p_{0}})}^{2 / 5} [\exp (\frac{2}{5} \frac{S_{2}}{n R}) - \exp (\frac{2}{5} \frac{S_{1}}{n R})]$	$(p, S : p_{1} S_{1} \to p_{1} S_{2}), d N = 0$
$W_{S 2, N} (p_{2}, p_{1})$	$=$	$+ \frac{3}{2} n R T_{0} [{(\frac{p_{2}}{p_{0}})}^{2 / 5} - {(\frac{p_{1}}{p_{0}})}^{2 / 3}] \exp (\frac{2}{5} \frac{S_{2} - S_{0}}{n R})$	$(p, S : p_{1} S_{2} \to p_{2} S_{2}), d N = 0$
$Q_{p 2, N} (S_{1}, S_{2})$	$=$	$+ \frac{5}{2} n R T_{0} {(\frac{p_{2}}{p_{0}})}^{2 / 5} [\exp (\frac{2}{5} \frac{S_{1}}{n R}) - \exp (\frac{2}{5} \frac{S_{2}}{n R})]$	$(p, S : p_{2} S_{2} \to p_{2} S_{1}), d N = 0$
$W_{p 2, N} (S_{1}, S_{2})$	$=$	$- n R T_{0} {(\frac{p_{2}}{p_{0}})}^{2 / 5} [\exp (\frac{2}{5} \frac{S_{1}}{n R}) - \exp (\frac{2}{5} \frac{S_{2}}{n R})]$	$(p, S : p_{2} S_{2} \to p_{2} S_{1}), d N = 0$
$W_{S 1, N} (p_{1}, p_{2})$	$=$	$+ \frac{3}{2} n R T_{0} [{(\frac{p_{1}}{p_{0}})}^{2 / 5} - {(\frac{p_{2}}{p_{0}})}^{2 / 5}] \exp (\frac{2}{5} \frac{S_{1} - S_{0}}{n R})$	$(p, S : p_{2} S_{1} \to p_{1} S_{1}), d N = 0$
$0$	$=$	$Q_{p 1, N} (S_{2}, S_{1}) + W_{p 1, N} (S_{2}, S_{1}) + W_{S 2, N} (p_{2}, p_{1})$
		$+ Q_{p 2, N} (S_{1}, S_{2}) + W_{p 2, N} (S_{1}, S_{2}) + W_{S 1, N} (p_{1}, p_{2})$	$(p S : 11 \to 12 \to 22 \to 21 \to 11), d N = 0$
$Q_{N}$	$=$	$Q_{N} (\to) + Q_{N} (\leftarrow)$
	$=$	$+ \frac{5}{2} n R T_{0} [{(\frac{p_{1}}{p_{0}})}^{2 / 5} - {(\frac{p_{2}}{p_{0}})}^{2 / 5}]$
		$\times [\exp (\frac{2}{5} \frac{S_{2}}{n R}) - \exp (\frac{2}{5} \frac{S_{1}}{n R})]$	$(p S : 11 \to 12 \to 22 \to 21 \to 11), d N = 0$
$W_{N}$	$=$	$W_{N} (\leftarrow) + W_{N} (\to)$
	$=$	$- \frac{5}{2} n R T_{0} [{(\frac{p_{1}}{p_{0}})}^{2 / 5} - {(\frac{p_{2}}{p_{0}})}^{2 / 5}]$
		$\times [\exp (\frac{2}{5} \frac{S_{2}}{n R}) - \exp (\frac{2}{5} \frac{S_{1}}{n R})]$	$(p S : 11 \to 12 \to 22 \to 21 \to 11), d N = 0$

PCRT.I.G.02

02 (N,p,S)-Koordinatensystem

Navigationsmenü

Suche